use the regular expression validator. The validation expression would be:

^20\.20\.30\.(25[0-5]|2[0-4][0-9]|[0-1]{1}[0-9]{2}|[1-9]{1}[0-9]{1}|[0-9])$

A RegEx Validator see:

docs.aspng.com/.../webvalidation.aspx#regex

^(25[0-5]|2[0-4][0-9]|[0-1]{1}[0-9]{2}|[1-9]{1}[0-9]{1}|[1-9])\.(25[0-5]|2[0-4][0-9]|[0-1]{1}[0-9]{2}|[1-9]{1}[0-9]{1}|[1-9]|0)\.(25[0-5]|2[0-4][0-9]|[0-1]{1}[0-9]{2}|[1-9]{1}[0-9]{1}|[1-9]|0)\.(25[0-5]|2[0-4][0-9]|[0-1]{1}[0-9]{2}|[1-9]{1}[0-9]{1}|[0-9])$ 

With the Rehex can you allow two dff values i.e.

A ip addy 20.20.30.x and allow 20.20.20.X ?

Is that possible cause in that col I have values like the following

20.20.30.1

20.20.30.3

20.20.30.4

20.20.20.1

20.20.20.2

20.20.20.6

I need to validate  both the 20.20.30.x and the 20.20.20.x

Any ideas?

You could use a RegularExpressionValidator with a ValidationExpression of:

^20.20.30.\d{1,3}$

To learn more about regular expressions, check out the articles at:
www.4guysfromrolla.com/.../...larExpressions.shtml

You've gotten a lot of answers and I think they've all been close.
Let me try to answer all of your questions:

Can you use a regular expression to validate:
20.20.20.X and 20.20.30.X

Yes, of course. I suggest it isn't worth doing, but it is possible
to do. I would take the following approach and use a custom
validator.

The first part of the expression is simple because you have two fixed
sets of networks: 20.20.30 and 20.20.20

I would still do this with a regular expression:
20\.20\.[23]0\.(\d){1,3}

20\.20\.[23]0\. this will match either 20.20.30 or 20.20.20

The (\d){1,3} will match any 1-3 digit number. I suggest a custom
validator to use that match ($1) and make sure 0 < $1 < 256 (make
sure it's in the valid range for an IP.

You could do it with a regular expression, it would look pretty
obnoxious. I say use tools where they make sense (like IsDate()
instead of a 4 line regular expression to validate  date...). Plus I
think this way will make more sense in the long run when you or
someone else is looking back on your code.